skip to main content


Search for: All records

Creators/Authors contains: "Roshan, Saeed"

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

  1. Abstract

    Cadmium (Cd) is a trace metal whose distribution in the ocean bears a remarkable resemblance to the nutrient phosphate (PO43−). This resemblance has led to the use of Cd as a proxy for ocean nutrient cycling in paleoceanographic applications, but the processes governing the cycling of Cd in the modern ocean remain unclear. In this study, we use previously published Cd observations and an Artificial Neural Network to produce a dissolved Cd climatology that reproduces the observed subtle deviations between the Cd anddistributions. We use the Cd andclimatologies, along with an ocean circulation inverse model, to diagnose the biogeochemical sources and sinks of dissolved Cd and. Our calculations reveal that dissolved Cd, like, is removed in the surface ocean and has a source in the subsurface, consistent with the simultaneous incorporation of Cd andinto sinking organic particles. However, there are also contrasts between the cycling of dissolved Cd andIn particular, thesurface export ratio varies 8‐fold across latitudes, reaching highest values in the iron‐limited sub‐Antarctic Southern Ocean. This depletes Cd relative toin the low‐latitude thermocline while adding excess Cd to deep waters by the regeneration of Cd‐enriched particles. Also, Cd tends to regenerate slightly deeper thanin the subsurface ocean, and theregeneration ratio reaches a maximum at 700–1,500 m. These contrasts are responsible for a slight concavity in therelationship and should be considered when interpreting paleoceanographic Cd records.

     
    more » « less
  2. Abstract

    Copper (Cu) is a biologically important trace metal for marine plankton, but it is also toxic at high concentrations. Understanding the global distribution of Cu and the processes controlling its cycling in the ocean is important for understanding how the distribution of this important element can respond to climate change. Here, we use available observations of dissolved copper, an artificial neural network, and an ocean circulation inverse model, to derive a global estimate of the three‐dimensional distribution and cycling of dissolved Cu in the ocean. We find that there is net removal by bio‐assimilation and/or scavenging of dissolved Cu in the surface ocean at a rate of ~1.7 Gmol yr−1and that both the concentration and export of dissolved Cu are highest in the Southern Ocean. In the subsurface above the near‐sediment layer, dissolved Cu is removed at a net rate of ~2.4 Gmol yr−1, consistent with scavenging onto sinking particles, contributing to an increase in the flux of particulate Cu with depth. This removal of Cu by scavenging in the interior ocean is balanced by a net near‐sediment source of dissolved Cu, which sustains a gradual increase in the concentration of dissolved Cu with depth. Globally, this net near‐sediment source is estimated at ~2.6 Gmol yr−1in the deep ocean and ~0.8 Gmol yr−1along continental shelves and slopes. Our results suggest an active oceanic dissolved Cu cycle with a mean internal ocean residence time of ~530 years, highlighting the potential for climate‐driven changes in the marine Cu cycle.

     
    more » « less